teams in spain: (superliga)
CG Puigcerdà (Puigcerdà)
Horcona CH Jaca (Jaca)
CH Txuri-Urdin (San Sebastián) (record champion)
CH Vielha (Vielha e Mijaran)
FC Barcelona (Barcelona)
Majadahonda HC (Majadahonda)
CH Villalba (Vilalba)
hockey in spain has it's tradition only near the pyrenees, especially in basque country.
http://www.hockeyhielo.com/ <- website in spanish
that's all i know about spanish hockey
portugal is member of the IIHF, but i don't think that they have a league.