I have the 10 greatest games. Some of the games are awesome... leaves you thinking about the few it missed though
Highlights are the 60 cup finals (Last Maurice Richard Game)
Dominant teams of the 70's (Including the legendary new years classic, where the habs stood toe to toe, with the supposed CSKA team that was left holding on for dear life on the draw)
1984's Good Friday Massacre, featuring one hell of an intense match against the nords.
The 86 & 93 Cup finals.
Heritage Classic (wish they added the old timers game before the main game... Im a sucker for that lol)
& '08's biggest come back in team history (5-0 to a 6-5 win against the Rags)
I have both, seen most of the 10 games, very little of the 100 year anniversary video.
The 10 greatest games is literally just that. The 10 full games (not highlights), very little new material (every game has a brief interview with a player/coach involved in the game before, and that's it). Spoiler alert, they win them all (except the Red Army, which is a tie). Some of the games have been listed already, but I think the last game at the forum is probably one that is not replayed often on TV. I recall it had the ceremony as well.
I haven't gone completely through the 100 year anniversary yet, but from what I have seen they have a brief clips dedicated to each Stanley Cup winning team. Even though I still need to see it, if your looking for something that tells the story of the Canadiens, this is for you.